Authors
Satoshi Kamiguchi, Kiyotaka Asakura, Tamaki Shibayama, Tomoko Yokaichiya, Tatsushi Ikeda, Akira Nakayama, Ken-ichi Shimizu, and Zhaomin Hou
Abstract
The development of new catalysts with high N2 activation ability is an effective approach for low-temperature ammonia synthesis. Herein, we report a novel angstrom-size molybdenum metal cluster catalyst for efficient ammonia synthesis. This catalyst is prepared by the impregnation of a molybdenum halide cluster complex with an octahedral Mo6 metal core on HY zeolite, followed by the removal of all the halide ligands by activation with hydrogen. In this activation, the size of the Mo6 cluster (ca. 7 Å) is almost retained. The resulting angstrom-size cluster shows catalytic activity for ammonia synthesis from N2 and H2, and the reaction proceeds continuously even at 200 °C under 5.0 MPa. DFT calculations suggest that N≡N bond cleavage is promoted by the cooperation of the multiple molybdenum sites.
Chemical Science: https://pubs.rsc.org/en/Content/ArticleLanding/2024/SC/D3SC05447K
